济南章丘一中2020-2021学年高二期中考试化学试卷(扫描版)
~~Ji:~:
1. '*--it<.t-.7)-~ I t-.C~#-~);fi,~ II t-.Ulo~#-~) ~~7)-, *- 100 7)- o :t1t<.at laJ 90 7)-4f o
2. ik~f~~$~Jj~,tf.$~-t J:.o
3. -*-1t<.t-..i..~:t1t<. JJ;J~:A.~Jl&..~#-·ti.!xd~ 1 ~--f, ~::::...-f, ~-=--f~-~, ~ Z!;l-f O
4.
>r:f:ti¥J~'@.W!f--HfilJ~l¥J.±~nlt::$t~~A~~'lfi!I
c. t:i.H l¥1*1J5f ~it~1JliAl¥1itii*~x*
D. & 1-t~ittl i±l 1¥J"FJ,ij:ftnm,pi:ftO~"l¥J~~.;;J:t.3::~ffi;j!:-l-7'J Si02
5. rJHJmr ,&ml!$t§!PJl¥J~
A !PJi.ll!!PJfi.$:fR!PJ~J;ti¥] HCl 5fll HNOs ::$t§Jtl5J~!lwJ1W:1¥J:lri¥J Na2COs Jfil?KDtfil
B. !PJr.ll!r ,~!lwJ1W:1¥J:lr1¥Jfk;fil5fllf¥Jfil::fr§Jtl5J~:lr 1 mol • L-1 1¥Jiik~Btm
C. !PJj.ll!jPJfi.$:fR 0. 5 mol • L-1 CH3 COOH 5fll 0. 25 mol • L-1 H2S04 ::$t§Jtl5J 0. 5 mol • L-1
i¥] NaOH m~Btm
D. !PJr.ll!!PJfi.$:f,g 0. 3 mol • L-1 HCl 5fll 0. 15 mol • L-1 H2S04 5J~ii~*iiifR~i:rilW:1¥JE
1!R.EBtm
• 21-l0-105Bl •
6. ~7](1ik--1' e ::1dm Will~$, f41vf A.ln 5¥Uffl it 1m JwJlll ~ ~~7.K i:p aM.11n~ -=r, Jt mullttm oo Elr$
Ca,b :l!gjg·tttl:El!;f:Jl), r!U1f~i3tr!iE~B91ik
A. b ~tlk1ftt/=(/tnlt
B. El!fmat a El!tliLt~~iEffi&lill
C. -.§t:atfaJJ§, b El!;f:Jlffliliffi'.~89 pH ~11£
'fi!l~rx~im
7. &Jill Fe(s)+C02 (g)~FeO(s)+CO(g), 700 °Cat ,K=l. 47; 900 °Cat ,K=2. 150 r!UiJt.
r!iE~B91ik
A. it&Jilljgjf_k~&lill
B '*i;:; r+O
10. r1u~r~~:1:Jl!~a9tta~~iE~ 891ik
A. ~~ffl Jtfnf!kJt ~3tE-ml~A~1mt~ i:p, fflJt*ffir~:k:i:E(.ifil
B. ffl~Jt-ftffttlk,ilJJt-ftiEtlk,~JtfnilJJt ffl~~ffi~miA CuS04 ffi'.~i:p ,ilJJt M:i::!:~:1111
C. ~ilJJtmiA~ltftf!kffi'.tii:j:i ,ffl)t*ffi~nlt-~f!k
D. ~~*'1if.kA~1f~~B9iJff i:p, :1JllAJL~ttttfflm~, r~E(.ifila9i!$:1Jll'l1c
=,~~~=*~~ 5 Jj~ 9 ~/J~ 4 ~.~ 20 ~o ~/J~~-,t-§Ji;p:;§",t-~!Pif~~~~~>,}<,~
alJ~X'lf~ 4 ~.~X'lf1§~~~i 2 ~.~~ffl'a{j~ 0 ~o
11. B~:C1)2Zn(s)+02(g)=2ZnO(s) L'::!.H=-696. 6 kJ • mol-1 ;
(2)4Ag(s)+02(g)=2Ag20(s) L'::!.H=-62. 0 kJ • mol-1 ;
1 1 1 _!j,{tl 2 Zn(s)+2 Ag20(s)=2 ZnO(s)+Ag(s)ff9 L'::!.H •r
A. -158. 65 kJ • mol-1
C. -317. 3 kJ • mol-1
B. +379. 3 kJ • mol-1
D. +317. 3 kJ • mol-1
• 21-10-105Bl •
12. &$!. 2NO(g)+2COCg) ilitJf!J 2C02Cg)+N2Cg) t.H %-r zrsJ i~~1:. 1-t~ &JiiZ a"J1ii.1Hi, f$::faJ:rr~Jl 1iitm, i~~ ~1:. :rrt:Jc@U.i a"J %-r, f$ ::faJ m
11:%-r, i5I! tf mi% r ~ mt ffl 1-t %-r FJr $ ~ 1;Jt a"J :Ii 1it ~i JJt a"J i~ fl ri~ ffl 1-t i~ , A~ w. ::faJ
kJ • mol-1 ,ifiAlixi~OO LOO 2 .#@J~r3ftlfi:il~:
.!iJ.ilI!l&J(t,J
-~,1i~:li(E1)
1:1.iil!l&la"" ="~"<"> o; 1±moc:1g TA *' TB xtliila"1f~1ft~ K CA)*'
K(B) r:p ,t5t:f(99~--
A.~:f(n(HCD
C. {J!Jt.J]!:fkf 99{l1tJflJ
t/min 0
n(Clz)/10-3 mol 0
B. ±i:f( nC02)
D.f$~ H20
2.0 4.0 6.0
1. 8 3. 7 5. 4
8.0
7. 2 it. 2. 0~6. 0 min 17'1 ~ Cl2 99!1w)Eft99:§:1£1t*~89&J.J:ll~$: (~ mol • min,-- 1
---
j;-;~{il.) 0
(4)Cl2 J=flit,rz,'.§Jtl:lffl Cb tiJ-fi~B~891t~::1fW5:-t: ---
• 21-10-105Bl •
~ +ffi~~
H2C03 K1 =4. 4X10-7 K2=4. 7x10-11
CsH50HC*®) K=l. lXl0-10
CH3CQOHC!m~) K=l. 75Xl0-5
H3As04 K1=6.ZX10-3 K2=l. zx10-1 K3=3.1Xl0-12
@1Ff~Ul'i:iJ~:
(1):iJ01.km$, §~ (:l;it",f,@Jt!:"M"trP~J")sj~Ma{J~~ ,K {]![ (:f:j;":f:~:k""~,j" --- ---
M"~1t") o
(2) H3As04 a{J~=tP'~~1Tl:£:i:t:;fg ,x;f J.ilZB{J~~JflffeJ1fH:ll:*ifs:i:tK2 = ------
C4)il1HJitt.*i:pa{J~~Jf~1il~,'.!ef ili Na3As04 m~i:p:iJaA:i:J:iia{Jl'Mat ,Jii:1:.&J.ilZB9~r
:1f;J;£:i:t: ---------
( 5 )~it-1-mf iti~!Ji!JiiiE~M !gl}Ma{JM't:H!U~: ------------
19. (12 :fr)ffl:ftal!l~iiu!:fi~-~!Ji(a,b,c,d :l:!g:;Jgis~;J:Jk.) ,f;ltm:J'fa{J~ 4 !il.~flilf.f~,Jt,µ!q:J{:f:!g
jg 500 mL,~j;t:l:!g:;fg 2 mol • L-1:
rn£,J Ail B;fl!!f
1 NaOHmt-!1i CuBr2 m~ a
z AgN03 ?$~ NaCl ~:$t-!1i
3 CuS04 mt-!1i CuClz m~ A B
4 A!Cl3 mt-!1i Na2 S04 f$t-!1i
Cl) I ft at , a, b, c, d ~ fliLt:l:!g~ 4. f2!s: !'° 1:. , fllU mti a{]~ fli¥~)ik_t;r£ !mill i:p a{]~ ti!. o
(2)m:J'i~ 1 !il.~-~at, ~-:i:J:;j;ji=p~~;j:JkJ:a{J~;j:Jk&J.ilZ:;Jg a*&: -------
; b ;j:Jk : ; dlk : ---- -------
; d flk: ---- -----------
( 3) m *~ 2 ti!.~fiW~at, ~ b tRffrili 2 g ~fi1¥1'°*1M ,a f&l:ffrilir"°*1B9Jffrii::f;; g;
J&. OH-!.¥; Cb B9&J.ilZ)
c 4)~*~ 3 ri!.~fiW~at, ~ a,c Wilt&~fi1¥1'°4wJa{JJffriitrHfat, b tR%11 d tR1'°1:.sg4,f*f*fJlrt
::f;; (fPjy!!fPJff"F) 0
20. 02 :fr) Z:,'.f$Jik~nlt~irh>1~{Q.~it4°*1-~Z:,'.1$a{Jitif2!s:, 1:ff Q.{ S3Ttt~flirf,~J4i o
.±.&J.ilZ: C4 H10 Cg, iET'.1;%)~C2 H4 Cg) +C2 H6 Cg) t:.H1
iU&J.ilZ:C4H10 (g,iET'.1;%)~CH4 Cg) +c3 H6 Cg, pg'./$) l:.H2
• 21-10-105Bl •
I I
@1 lFFJtl l'iiJ ®!:
o Ht~ J::, tiffiJEiJi mt a 1¥1 ti~t
n4~n)t~,~nlt~Pf~ffi1'11*!fmlffta'-Jffix1fci~:lto "}"~1'125 °C ,101 kPa r JL#~t!L!fma'-J
~nlt~:
!fml.m l:fltt z:.tt z:.~ pg~ iETtt JFTtt
··.
1:.nl!:~/kJ • mol-1 -75 -85 +52 +20 -125 -132
®J::~&J.ilPf1 , ~H2 = kJ • mol- 1 o
C2)-JErllilocr ,tE'm~Wl~~:ffi:pritA-JE:ltiET*%~~&J.ill~nltZ.i/$o rftl'tfR~aJB*
&J.ill~IUV-~tlt~a o
A. Efi{#Woc1*t~~1t
B cCC2H4)cCC2H6) 1o+±-r;,rr;
' c(C4H10) PKJ-j"'/l"::s,:..
c. E(.{#ff5£~1t
D. iE T ~5tfll¥Ji $5¥1l Z. *%~nltJ1$ffi ~
(3) rPJ'tfiffWl~~:ffi:j:rJ'EAiET~ ,:r±:,,,, JE~{4C~oc,{11HtJf!J]kff5j~) r~~&J.ill, ;t[~IP]at
l'a.J pg .~HlJZ.1$~$.~rlllloca?#!!"""
!+""*6"9"*@!:A" """" *@*6"9*@!*6:""9"A":!"""
!/'!!"34!!""#56!!""
!""A"(8:# $%+ A9 9A(8:"#
+ !"""#$!A9 "$!A(8:"#
+ "
$!A"(8:#
+ " !"""
!)"*,A%:A#A"*:)#*A)*::A#A)(8:+!"""
!+"(8:)#
+ 9"*A) """*::A A"(8:#
+ 9"*A)*::# !"""
!%"789:;<=>?@ABCD#E;%FGH@IJK$LMNOPC%LMNOP6QR%STE
;@;UVW:;@;U!,-./012%"""
!0'!!"+!"""
!"""A":9"B """# A"&9":A# !,"A9 9"B """# A"&%!""#+:A# #+B """# "A":9:"&!!""#
*7"9 9"B """# *7!!""#"&C# #"B """# &C"!!""
!)"".!"""#$'%!"""
!+"!D"!"""
"$'!!""XY!"""
#9.$!"""
!""&*!"""
!)"*- !"""
!+""$1!%!"""
#+'%!"""